Low-gloss thermoplastic composition

ABSTRACT

A composition for extruding or injection molding low-gloss articles exhibiting improved color retention and mechanical properties as compared with conventional pigmented or painted PVC or TPO resins includes polypropylene, a thermoplastic polyolefin elastomer in an amount sufficient to impart superior impact resistance and at least one particulate delustering agent in an amount sufficient to provide low-gloss without sacrificing impact strength.

CROSS-REFERENCE TO RELATED APPLICATIONS

This application is a continuation-in-part of application Ser. No.16/601,695, filed Oct. 15, 2019, which is incorporated herein byreference in its entirety.

FIELD OF THE DISCLOSURE

Disclosed are low-gloss thermoplastic compositions exhibiting anexcellent combination of strength and weatherability.

BACKGROUND OF THE DISCLOSURE

Low-gloss thermoplastic surfaces can often provide favorable aestheticsin particular outdoor applications, such as fence posts, rails andbalusters; decking, window frames, and door frames. Such products aretypically extruded and require either mechanically delustering thesurface or adding large volumes of delustering agents, such as silica,silicates, alumina or the like. Mechanical delustering involves an addedstep that increases cost. Adding large volumes of delustering agents canadversely affect impact strength.

Another problem with conventional low-gloss thermoplastic articles isthat they tend to rapidly lose color (i.e., fade) when exposed tosunlight and precipitation. This problem has been overcome by paintingthe exposed surfaces of the articles. However, this adds significantlyto the cost of the product and often requires restoration (touch ups)after installation to cover any underlying surfaces exposed by chipping,flaking or peeling of paint from the surface.

SUMMARY OF THE DISCLOSURE

There is disclosed a thermoplastic composition that can be extruded ormolded to provide articles exhibiting an excellent combination ofweatherability, mechanical properties and low-gloss. The compositioncomprises about 5% to about 90% polypropylene by weight, about 5% toabout 90% of at least one thermoplastic polyolefin elastomer by weight,about 0.1% to about 10% polybutylene by weight, and about 0.2% to about25% of at least one particulate delustering agent by weight, wherein thepolypropylene, thermoplastic polyolefin elastomer, polybutylene,particulate delustering agent and pigment comprise at least 90% of theweight of the composition.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a graphical illustration of color retention as a function ofXenon arc lamp radiation exposure for a yellow plastic article inaccordance with this disclosure compared with a yellow PVC article.

FIG. 2 is a graphical illustration of color retention as a function ofXenon arc lamp radiation exposure for two silver plastic articles inaccordance with this disclosure compared with a silver PVC article.

FIG. 3 is a graphical illustration of color retention as a function ofXenon arc lamp radiation exposure for a silver plastic article inaccordance with this disclosure compared with a silver paintedcommercially available thermoplastic olefin.

DESCRIPTION OF THE PREFERRED EMBODIMENTS

The low-gloss thermoplastic compositions of this disclosure includepolypropylene in an amount sufficient to provide an excellentcombination of scratch resistance and heat deflection temperature (e.g.,greater than 200° F.), at least one thermoplastic polyolefin rubber(elastomer) in an amount sufficient to impart excellent impactresistance without significantly reducing scratch resistance,polybutylene in an amount that enhances deglossing and impactresistance, at least one particulate delustering agent in an amountsufficient to provide an aesthetically desired low-gloss surface withoutadversely affecting impact strength, and at least one dye or pigment inan amount sufficient to impart a desired color (i.e., hue, tint, toneand shade).

The polypropylene can be a homopolymer of propylene, a copolymer ofpropylene and ethylene, or a copolymer of propylene and an alpha-olefinco-monomer. The polypropylene copolymer, when used, may be comprised ofgreater than 95% propylene-derived units, more preferably greater than98% propylene-derived units, and most preferably greater than 99%propylene-derived units. The preferred polypropylenes have acrystallinity of at least 50%, more preferably at least 80% and mostpreferably greater than 90%, as determined by differential scanningcolorimetry.

The low-gloss thermoplastic compositions of this disclosure may comprisefrom about 5% polypropylene to about 90% polypropylene by weight. It isbelieved that heat deflection temperature and scratch resistance aresomewhat compromised when the composition comprises less than 40%polypropylene. Preferably, the composition comprises about 80% or lesspolypropylene by weight, primarily to allow for sufficient syntheticelastomer (or rubber) to impart excellent impact resistance, andsufficient particulate delustering agent to achieve a desired low-gloss.A preferred amount of polypropylene is 10% to 80% of the composition byweight, and more preferably 40% to 80% by weight of the composition.

Suitable thermoplastic polyolefin elastomers are saturated (non-curableor non-vulcanizable) rubbers that are compatible with polypropylene,such that the blend exhibits macroscopically uniform physicalproperties. Preferred elastomers include ethylene-propylene rubber (EPM)and ethylene-propylene-diene rubber (EPDM). Other thermoplasticelastomers that can be used include ethylene/alpha-olefin copolymersobtained by polymerization of ethylene with an alpha-olefin having 3 to12 carbon atoms (e.g., butane, 1-hexene, 1-methylpentane, 1-heptene,1-octene, 1-nonene, 1-decene, 1-undecene and 1-dodecene). Combinationsof thermoplastic polyolefin elastomers can be used. For example, acombination of EPDM rubber and an ethylene/alpha-olefin copolymer can beused. The thermoplastic polyolefin elastomer is present in an amount offrom 5% to 90% by weight, from 5% to 70% by weight or from 5% to 60% byweight.

Polybutylene is added to the low-gloss thermoplastic compositions ofthis disclosure in an amount that enhances deglossing and impactresistance without sacrificing other desired properties. This amount canbe as little as about 0.1% by weight and as high as about 10% by weight,with a preferred range being from about 0.5% to about 10% or from about1% to about 10%.

Examples of particulate delustering agents that can be used in thedisclosed low-gloss thermoplastic compositions include fumed silica,talc, mica, calcium carbonate, calcium oxide, calcium hydroxide,magnesium oxide, magnesium sulfate, aluminum hydroxide, barium sulfate,glass microparticles, clay, dolomite and alumina. The delustering agentis typically in the form of a fine particulate having a sizedistribution in the micrometer or nanometer ranges (e.g., 100 nm to 100μm). It has been determined that low gloss can be achieved using loweramounts of particulate delustering agent(s) by using fumed silica,either alone or in combination with at least one other particulatedelustering agent. In addition to reducing gloss, particulatedelustering agents can have the added benefit of reducing cost and/orincreasing flexural modulus. However, higher amounts of particulatedelustering agents can cause reduced impact strength and/or reducedtensile strength.

The total amount of particulate delustering agents that is acceptabletypically is in the range of from about 0.2% to about 25% of the weightof the composition, preferably from about 1% to about 20%, and mostpreferably from about 5% to about 10%. It is also desirable that atleast one of the particulate delustering agents is fumed silica (e.g.,Aerosil® fumed silica from Evonik Industries) present in an amount offrom about 0.1% to about 5% by weight of the composition, morepreferably from about 1% to about 4%.

The low-gloss thermoplastic compositions of this disclosure are intendedto be used in articles having an exposed or displayed surface exhibitingdesirable appearance that is maintained after prolonged weathering. Inparticular, the compositions are formulated to maintain low-gloss andretain color after prolonged exposure to sunlight and precipitationwithout reliance on a surface coating (e.g., paint or clear coating). Assuch, the compositions disclosed herein contain from about 0.5% to about4% of at least one dye or pigment, more preferably from 1% to 2%, byweight of the composition. Examples of pigments that can be usedindividually or in coordination include titanium dioxide, carbon black,red iron oxide, black iron oxide, chromium oxide green and ultramarineblue. Examples of dyes include azo red dyes, quinacridone red dyes,anthraquinone red dyes, perylene red dyes, copper phthalocyanine blueand green dyes, isoindolineone orange and yellow dyes, and carbazoleviolet dyes.

The low-gloss thermoplastic compositions disclosed herein can, andpreferably do, include a nucleating agent that increases the rate ofcrystallization of polypropylene from a melted blend, such as duringextrusion or injection molding. Suitable nucleating agents include solidbicyclic dicarboxylic acid salts, such as bicyclo [2.2.1]heptane-2-carboxylic acid salt. A suitable amount of nucleating agent(e.g., a solid bicyclic dicarboxylate) is from about 0.1% to about 0.5%of the composition by weight.

The compositions of this disclosure may contain other component polymersor additives, such as flame retardants, lubricants, plasticizers, andweatherability enhancing agents in relatively modest and conventionalamounts. However, the amount of polypropylene, thermoplastic polyolefinelastomer, polybutylene particulate delustering agent(s), and pigment(s)and/or dye(s) comprise at least 90% of the weight of the disclosedcompositions, preferably at least 95%, and most preferably at least 98%.

The compositions of this disclosure can be used for producing variousarticles by injection molding or extrusion. Applications includedecking, fence posts and rails, window frames, door frames,architectural molding, and automotive parts that require a low-glossappearance, such as simulated wood trim, door handles, satin-nickelchrome accent trim and appliques. In certain applications, thecompositions disclosed herein can be co-extruded with a different baseresin composition to produce a laminate, or extruded or molded onto apreexisting solid substrate (e.g., aluminum or steel substrate).

The low-gloss thermoplastic compositions of this disclosure offerseveral advantages over the polyvinyl chloride (PVC) articles typicallyused for outdoor applications. These include lower density(approximately 40% lower than PVC compositions), superior weathering,superior impact resistance, superior scratch resistance, reduced cost,and higher heat deflection temperature (i.e., greater than 200° F. or230° F., as compared with 161° F. for PVC).

Comparative Xenon Arc Weatherometer testing of identically configuredsamples in accordance with this disclosure and painted TPO articlesshowed that the compositions, disclosed herein provide productsexhibiting superior color retention. FIG. 1 illustrates the change incolor (DE Reading) as a function of cumulative exposure toelectromagnetic energy from a Xenon arc lamp for yellow colored plasticarticles. A DE Reading less than 3.0 at 2500 Kj is considered acceptable(i.e., a passing grade). Comparative Xenon Arc Weatherometer testing wasalso performed on silver colored plastic articles. The results for thesilver parts are shown in FIG. 2. The results show that the yellowarticles in accordance with this disclosure (Croma 2115) exhibitedexcellent color retention, whereas the yellow PVC articles failed. Thesilver plastic article in accordance with this disclosure (Croma #1 andCroma #2) also exhibited superior color retention (i.e., low DE Reading)as compared with the silver PVC article.

The silver-colored plastic articles in accordance with this disclosurewere also tested for color retention under natural (free) weatheringconditions in Florida and Arizona for 2 years, with the resulting DEReading being 0.80 in Florida and 0.29 in Arizona after the 2 yearperiod. Even after 3 years of natural weathering in Florida, the silverarticles in accordance with this disclosure has a DE Reading of 0.76.

A silver pigmented article in accordance with this disclosure wassubjected to comparative testing with a silver painted commerciallyavailable thermoplastic olefin extrudate (TPO) using a Xenon ArcWeatherometer. The results illustrated in FIG. 3 show that the silverarticles of this disclosure (Spectra TPO) exhibit substantially superiorcolor retention (Delta E or DE Reading) as compared with theconventional silver painted TPO articles (Painted TPO).

Comparative testing also showed that identically configured (i.e., sizedand shaped) extrudes in accordance with this disclosure had lowerdensity (0.92 g/cm³) than the PVC articles (1.35 g/cm³), a lowercoefficient of liner thermal expansion (8.5-9.5) than the PVC articles(14.5), which also exhibits a substantially superior Gardner Impactstrength at 23° C. (320 in-lbs) as compared with 40 in-lbs for the PVCarticles. Comparative testing also indicates that the articles of thisdisclosure exhibited substantially better Gardner Impact at 23° C. (320in-lbs) that conventional painted thermoplastic olefin extrudes (160in-lbs). Scratch resistance for the articles in accordance with thisdisclosure was found to be comparable to that of PVC and conventionalthermoplastic olefin articles.

Excellent color retention was exhibited for a variety of differentcolored articles in accordance with this disclosure, including black,silver, redwood and cedar, all of which had Xenon Arc Weatherometer DEReadings of 0.83 or less at 2500 Kj.

While the present invention is described herein with reference toillustrated embodiments, it should be understood that the invention isnot limited hereto. Those having ordinary skill in the art and access tothe teachings herein will recognize additional modifications andembodiments within the scope thereof. Therefore, the present inventionis limited only by the claims attached herein.

What is claimed is:
 1. A low-gloss thermoplastic composition comprising:polypropylene in an amount of from 5% to 90% by weight; at least onethermoplastic polyolefin elastomer in an amount from 5% to 90% byweight; polybutylene in an amount of from 0.1% to 10% by weight; atleast one particulate delustering agent in an amount from 0.2% to 25% byweight; and wherein the polypropylene, thermoplastic polyolefinelastomer, polybutylene, particulate delustering agent and pigmentcomprise at least 90% of the weight of the composition.
 2. Thecomposition of claim 1, wherein the polypropylene is a homopolymer. 3.The composition of claim 1, wherein the polypropylene has acrystallinity of at least 50%.
 4. The composition of claim 1, whereinthe polypropylene is present in an amount from 10% to 80% by weight. 5.The composition of claim 1, wherein the polypropylene is present in anamount from 40% to 80% by weight.
 6. The composition of claim 1, whereinthe thermoplastic polyolefin elastomer comprises EPM.
 7. The compositionof claim 1, wherein the thermoplastic polyolefin elastomer comprisesEPDM.
 8. The composition of claim 1, wherein the thermoplasticpolyolefin elastomer comprises ethylene/alpha-olefin copolymer.
 9. Thecomposition of claim 1, further comprising at least one dye or pigmentin an amount from 0.005% to 4% by weight.
 10. The composition of claim1, wherein polybutylene is present in an amount from 1% to 10% byweight.
 11. The composition of claim 1, wherein the at least oneparticulate delustering agent includes fumed silica in an amount from 1%to 10% of the composition by weight.
 12. The composition of claim 11,wherein the at least one particulate delustering agent includes adelustering agent other than fumed silica.
 13. The composition of claim12, wherein the delustering agent other than fumed silica is selectedfrom talc, mica, calcium carbonate, calcium oxide, calcium hydroxide,barium sulfate, glass microparticles, clay, dolomite and alumina. 14.The composition of claim 1, wherein the at least one delustering agenthas particle sizes distributed in the range from 100 nm to 100 μm. 15.The composition of claim 1, wherein the at least one delustering agentis present in amounts from 5% to 10% by weight.
 16. The composition ofclaim 1, further comprising a nucleating agent that promotespolypropylene crystallization.
 17. The composition of claim 16, whereinthe nucleating agent is a solid bicyclic dicarboxylate present in anamount from 0.1% to 0.5% by weight.
 18. The composition of claim 1,wherein the polypropylene, thermoplastic polyolefin elastomer,polybutylene, particulate delustering agent and pigment comprise atleast 95% of the weight of the composition.
 19. The composition of claim1 shaped into an article by extrusion.
 20. The composition of claim 1,shaped into an article by injection molding.